Course Description
Electronic absorption Spectroscopy.
Term symbols- energies of atomic and Molecular transitions- Selection rule - Morse- potential energy diagram, electronic transitions-polarized absorption spectra-Nature of absorption spectra-nature of absorption spectra of transition metal complexes-Orgel diagram-Tanabe Sugano diagram, charge transfer spectra.
Infrared and Raman Spectroscopy.
Molecular vibrations- force constants-Molecular vibrations and absorption of Infrared radiations Raman Spectroscopy- polarized Raman lines, Use of symmetry considerations to determine the no of lines in IR and Raman Spectra- Spectra of gases- applications of Raman and Infrared spectroscopy- Selection rule in Inorganic structure determinations-Hydrogen bonding and infrared spectra-metal ligand and related vibrations.
Microwave spectroscopy.
Basic concept- rotation spectra of simple inorganic compounds- Classification of molecules - rigid rotor model, effect of isotopic substitution on transition frequencies & intensities non rigid rotor- stark effect nuclear and electron spin interaction and effect of external field- Applications of Micro wave Spectroscopy.
Nuclear Magnetic Resonance Spectroscopy.
Principle Instrumentation of NMR- the chemical shift- mechanism of electron shielding and factors contributing to the magnitude of chemical shift- Local & remote effect- spin spin splitting, applications of spin coupling to structural determination- double Resonance techniques- The contact and Pseudo contact shifts Factors affecting nuclear relaxation- anoverview of NMR of metal nuclear with emphasis on 195 pg. & 119sm NMR.
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Electronic absorption Spectroscopy. Term symbols- energies of atomic and Molecular transitions- Selection rule - Morse- potential energy diagram, electronic transitions-polarized absorption spectra-Nature of absorption spectra-nature of absorption spectra of transition metal complexes-Orgel diagram-Tanabe Sugano diagram, charge transfer spectra. Infrared and Raman Spectroscopy. Molecular vibrations- force constants-Molecular vibrations and absorption of Infrared radiations Raman Spectroscopy- polarized Raman lines, Use of symmetry considerations to determine the no of lines in IR and Raman Spectra- Spectra of gases- applications of Raman and Infrared spectroscopy- Selection rule in Inorganic structure determinations-Hydrogen bonding and infrared spectra-metal ligand and related vibrations. Microwave spectroscopy. Basic concept- rotation spectra of simple inorganic compounds- Classification of molecules - rigid rotor model, effect of isotopic substitution on transition frequencies & intensities non rigid rotor- stark effect nuclear and electron spin interaction and effect of external field- Applications of Micro wave Spectroscopy. Nuclear Magnetic Resonance Spectroscopy. Principle Instrumentation of NMR- the chemical shift- mechanism of electron shielding and factors contributing to the magnitude of chemical shift- Local & remote effect- spin spin splitting, applications of spin coupling to structural determination- double Resonance techniques- The contact and Pseudo contact shifts Factors affecting nuclear relaxation- anoverview of NMR of metal nuclear with emphasis on 195 pg. & 119sm NMR. |
Course ID: CHEM 564
| Credit hours | Theory | Practical | Laboratory | Lecture | Studio | Contact hours | Pre-requisite | 3 | 3 | 3 | - |
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